ETHYL 3-(2-FURYL)PROPIONATE

  • Name: ETHYL 3-(2-FURYL)PROPIONATE
  • CAS: 10031-90-0
  • Purity: 99%
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Details

Quality Manufacturer Supply High Purity 99% ETHYL 3-(2-FURYL)PROPIONATE 10031-90-0 with Reasonable Price

  • Molecular Formula: C9H12O3
  • Molecular Weight: 168.192
  • Vapor Pressure: 0.148mmHg at 25°C 
  • Refractive Index: n20/D 1.459(lit.)  
  • Boiling Point: 215.4 °C at 760 mmHg 
  • Flash Point: 92.3 °C 
  • PSA: 39.44000 
  • Density: 1.064 g/cm3 
  • LogP: 1.77530 

ETHYL 3-(2-FURYL)PROPIONATE(Cas 10031-90-0) Usage

Preparation

By direct esterification of the acid, which in turn is prepared by condensation of furfural with acetic anhydride and sodium acetate, followed by hydrogenation of the furacrylic acid

Taste threshold values

Taste characteristics at 15 ppm: pineapple, fruity, sweet, slightly spicy, tropical ripe and slightly jamy.

InChI:InChI=1/C9H12O3/c1-2-11-9(10)6-5-8-4-3-7-12-8/h3-4,7H,2,5-6H2,1H3

10031-90-0 Relevant articles

Prostaglandins and congeners. XVIII. Synthesis of cyclopentenolone precursors to prostaglandins from 2,5-dihydro-2,5-dimethoxyfurans

Floyd

, p. 1641 - 1643 (1978)

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One-Pot, Tandem Wittig Hydrogenation: Formal C(sp3)-C(sp3) Bond Formation with Extensive Scope

Devlin, Rory,Jones, David J.,Mcglacken, Gerard P.

, p. 5223 - 5228 (2020)

A one-pot, tandem Wittig hydrogenation o...

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Matsuno,Han

, p. 155 (1937)

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Preparation method of medium-and-long chain fatty carboxylic acid

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Paragraph 0040-0044, (2019/04/04)

The application discloses a preparation ...

Structure-Odor Correlations in Homologous Series of Mercapto Furans and Mercapto Thiophenes Synthesized by Changing the Structural Motifs of the Key Coffee Odorant Furan-2-ylmethanethiol

Schoenauer, Sebastian,Schieberle, Peter

, p. 4189 - 4199 (2018/05/01)

Furan-2-ylmethanethiol (2-furfurylthiol;...

NOVEL COMPOUNDS

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Page/Page column 96, (2008/12/06)

There is provided a compound of formula ...

10031-90-0 Process route

ethyl (E)-3-(2-furyl)prop-2-enoate
53282-12-5,53282-26-1

ethyl (E)-3-(2-furyl)prop-2-enoate

ethyl 3-(furan-2-yl)propanoate
10031-90-0

ethyl 3-(furan-2-yl)propanoate

Conditions
Conditions Yield
With hydrogen; Wilkinson's catalist; In tetrahydrofuran; at 45 ℃; for 18h; under 2585.81 Torr;
97%
With hydrogen; Lindlar's catalyst; In methanol; for 8h;
82%
With ammonium hydroxide; hydrogen; nickel; In ethanol;
80%
With ethanol; nickel; at 110 - 120 ℃; Hydrogenation;
With carbon monoxide; hydrogen; benzene; at 125 ℃; under 19123.2 Torr; Gegenwart von Octacarbonyldikobalt;
With sodium amalgam; ethanol; acetic acid;
With triethylsilane; silica gel; Wilkinson's catalyst; Yield given. Multistep reaction; 1.) benzene, room temperature, 8 h, 2.) petroleum ether, ethyl acetate;
ethanol
64-17-5

ethanol

3-(2-furyl)acrylic acid p-tosylhydrazide

3-(2-furyl)acrylic acid p-tosylhydrazide

ethyl 3-(furan-2-yl)propanoate
10031-90-0

ethyl 3-(furan-2-yl)propanoate

Ethyl p-toluenesulfinate
1858-86-2,59153-38-7,59203-02-0,112458-71-6

Ethyl p-toluenesulfinate

ethyl (E)-3-(2-furyl)prop-2-enoate
53282-12-5,53282-26-1

ethyl (E)-3-(2-furyl)prop-2-enoate

Conditions
Conditions Yield
With toluene-4-sulfonic acid; at 79 ℃; for 60h;
19%
62%
21%

10031-90-0 Upstream products

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    53282-12-5

    ethyl (E)-3-(2-furyl)prop-2-enoate

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    3-(2-furyl)-propanoic acid chloride

10031-90-0 Downstream products

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    ethyl 4-oxoheptanoate

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