Details
Cost-effective and customizable Ethyl 2-propylacetoacetate 1540-28-9 supplier
- Molecular Formula: C9H16O3
- Molecular Weight: 172.224
- Vapor Pressure: 0.0934mmHg at 25°C
- Refractive Index: 1.424
- Boiling Point: 224 °C at 760 mmHg
- PKA: 12.17±0.46(Predicted)
- Flash Point: 82.4 °C
- PSA： 43.37000
- Density: 0.967 g/cm3
- LogP: 1.55480
Ethyl 2-propylacetoacetate(Cas 1540-28-9) Usage
InChI:InChI=1/C9H16O3/c1-4-6-8(7(3)10)9(11)12-5-2/h8H,4-6H2,1-3H3
1540-28-9 Relevant articles
Calreticulin transacetylase: A novel enzyme-mediated protein acetylation by acetoxy derivatives of 3-alkyl-4-methylcoumarins
Jalal, Sarah,Chand, Karam,Kathuria, Abha,Singh, Prabhjot,Priya, Nivedita,Gupta, Bhavna,Raj, Hanumantharao G.,Sharma, Sunil K.
, p. 131 - 136 (2012)
Our earlier investigations culminated in...
Asymmetric Aza-Wacker-Type Cyclization of N-Ts Hydrazine-Tethered Tetrasubstituted Olefins: Synthesis of Pyrazolines Bearing One Quaternary or Two Vicinal Stereocenters
Kou, Xuezhen,Shao, Qihang,Ye, Chenghao,Yang, Guoqiang,Zhang, Wanbin
supporting information, p. 7587 - 7597 (2018/06/04)
We have developed an asymmetric aza-Wack...
Novel Electrophilic and Photoaffinity Covalent Probes for Mapping the Cannabinoid 1 Receptor Allosteric Site(s)
Kulkarni, Pushkar M.,Kulkarni, Abhijit R.,Korde, Anisha,Tichkule, Ritesh B.,Laprairie, Robert B.,Denovan-Wright, Eileen M.,Zhou, Han,Janero, David R.,Zvonok, Nikolai,Makriyannis, Alexandros,Cascio, Maria G.,Pertwee, Roger G.,Thakur, Ganesh A.
, p. 44 - 60 (2016/01/29)
Undesirable side effects associated with...
ALLOSTERIC MODULATORS OF THE CANNIBINOID 1 RECEPTOR
-
Paragraph 0269, (2015/03/13)
The present technology relates to compou...
Theoretical investigation of the reaction of dialkylzincs with α-alkoxycarbonyl radicals. Evaluation of α-bromoacrylates as radical acceptors in radical-polar crossover processes
Vibert, Fran?ois,Maury, Julien,Lingua, Hugo,Besson, Eric,Siri, Didier,Bertrand, Michèle P.,Feray, Laurence
, p. 8991 - 9002 (2015/11/02)
The evaluation of ethyl α-bromoacrylate ...
1540-28-9 Process route
-
-
141-97-9
ethyl acetoacetate
-
-
107-08-4
1-iodo-propane
-
-
1540-28-9
ethyl 2-propylacetoacetate
| Conditions | Yield |
|---|---|
|
ethyl acetoacetate;
With
sodium;
In
ethanol;
for 0.5h;
Inert atmosphere;
Reflux;
1-iodo-propane;
for 2.5h;
Reflux;
Inert atmosphere;
|
78%
|
|
ethyl acetoacetate;
With
sodium;
In
ethanol;
at 10 ℃;
for 0.5h;
Inert atmosphere;
Reflux;
1-iodo-propane;
In
ethanol;
for 12h;
Inert atmosphere;
Reflux;
|
78%
|
|
ethyl acetoacetate;
With
sodium ethanolate;
In
ethanol;
at 20 ℃;
for 0.166667h;
1-iodo-propane;
In
ethanol;
for 3h;
Reflux;
|
70%
|
|
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
In
benzene;
for 3h;
Ambient temperature;
|
48%
|
|
With
ethanol; sodium;
|
|
|
Multistep reaction;
(i)
|
|
|
With
lithium hydroxide;
Yield given. Multistep reaction;
1.) THF, 55 deg C, 15 min, 2.) THF, 24 h;
|
|
|
With
sodium ethanolate;
In
ethanol;
Heating;
|
|
|
ethyl acetoacetate;
With
sodium hydride;
In
tetrahydrofuran; mineral oil;
at 20 ℃;
for 0.5h;
1-iodo-propane;
In
tetrahydrofuran; mineral oil;
for 6h;
Reflux;
|
-
-
5459-35-8
2-bromo-acrylic acid ethyl ester
-
-
13411-48-8
1-(trimethylsilyl)ethanone
-
-
557-20-0
diethylzinc
-
-
1540-28-9
ethyl 2-propylacetoacetate
| Conditions | Yield |
|---|---|
|
In
n-heptane; dichloromethane;
at 20 ℃;
for 18h;
Inert atmosphere;
|
80%
|
1540-28-9 Upstream products
-
141-97-9
ethyl acetoacetate
-
106-94-5
propyl bromide
-
107-08-4
1-iodo-propane
-
1007476-32-5
sodium ethyl acetylacetate enolate
1540-28-9 Downstream products
-
2298-28-4
N,N'-bis(4-hydroxyphenyl)urea
-
53091-92-2
2-propyl-acetoacetic acid p -toluidide
-
1219-99-4
N,N'-bis(4-chlorophenyl)urea
-
1227-44-7
N,N'-bis(4-methoxyphenyl)urea
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