Benzyl propionate

  • Name:Benzyl propionate
  • CAS:122-63-4
  • Purity:99%
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Details

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  • Molecular Formula:C10H12O2
  • Molecular Weight:164.204
  • Appearance/Colour:Clear colourless liquid 
  • Vapor Pressure:0.105mmHg at 25°C 
  • Melting Point:221-223 °C 
  • Refractive Index:n20/D 1.497(lit.)  
  • Boiling Point:221.8 °C at 760 mmHg 
  • PKA:0[at 20 ℃] 
  • Flash Point:96.1 °C 
  • PSA：26.30000 
  • Density:1.034 g/cm3 
  • LogP:2.13980 

Benzyl propionate(Cas 122-63-4) Usage

Preparation

By esterification of benzyl alcohol with propionic acid.

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 5678, 1990 DOI: 10.1021/jo00309a007Synthetic Communications, 25, p. 2435, 1995 DOI: 10.1080/00397919508015447Synthesis, p. 853, 1990 DOI: 10.1055/s-1990-27034

Biochem/physiol Actions

Taste at 30 ppm

Taste threshold values

Taste characteristics at 15 ppm: fruity, sweet, green and powdery with a ripe berry nuance.

InChI:InChI=1/C10H12O2/c1-2-10(11)12-8-9-6-4-3-5-7-9/h3-7H,2,8H2,1H3

122-63-4 Relevant articles

Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers

Ye, Yang,Chen, Haifeng,Sessler, Jonathan L.,Gong, Hegui

, p. 820 - 824 (2019)

Zn-mediated reduction of readily accessi...

Zinc promoted mild and efficient method for the esterification of acid chlorides with alcohols

Yadav,Reddy, Gondi Sudershan,Srinivas, Dale,Himabindu, Konuru

, p. 2337 - 2342 (1998)

The esterification of variety of acid ch...

Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes

Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,Shi, Renyi,Chiang, Chien-Wei,Lei, Aiwen

, p. 6852 - 6855 (2017)

A metal-free radical oxidative carbonyla...

Fully recyclable Br?nsted acid catalyst systems

Watson, Christopher B.,Kuechle, Adrianna,Bergbreiter, David E.

, p. 1266 - 1273 (2021/02/26)

Homogeneous and heterogeneous sulfonic a...

Palladium-Catalyzed Direct Dicarbonylation of Amines with Ethylene to Imides

Kuai, Chang-Sheng,Wang, Le-Cheng,Wu, Xiao-Feng,Xu, Jian-Xing

supporting information, (2022/01/04)

The selective and effective conversion o...

Regioselective 2-alkylation of indoles with α-bromo esters catalyzed by Pd/P,P=O system

Li, Bowen,Tang, Wenjun,Tian, Duanshuai,Tian, Wei

, (2021/08/13)

A palladium-catalyzed 2-alkylation of in...

A Mild, General, Metal-Free Method for Desulfurization of Thiols and Disulfides Induced by Visible-Light

Qiu, Wenting,Shi, Shuai,Li, Ruining,Lin, Xianfeng,Rao, Liangming,Sun, Zhankui

supporting information, p. 1255 - 1258 (2021/05/05)

A visible-light-induced metal-free desul...

122-63-4 Process route

benzyl proprionate
122-63-4

benzyl proprionate

propionic acid
802294-64-0,79-09-4

propionic acid

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Conditions
Conditions Yield
at 170 - 180 ℃;
(S)-3-((2S,3S)-3-Hydroxy-2,4,4-trimethyl-pentanoyl)-4-isopropyl-oxazolidin-2-one

(S)-3-((2S,3S)-3-Hydroxy-2,4,4-trimethyl-pentanoyl)-4-isopropyl-oxazolidin-2-one

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

benzyl proprionate
122-63-4

benzyl proprionate

pivalaldehyde
630-19-3

pivalaldehyde

Conditions
Conditions Yield
lanthanum(III) iodide; In tetrahydrofuran; Ambient temperature;

122-63-4 Upstream products

  • 137-40-6
    137-40-6

    sodium proprionate

  • 100-44-7
    100-44-7

    benzyl chloride

  • 802294-64-0
    802294-64-0

    propionic acid

  • 100-51-6
    100-51-6

    benzyl alcohol

122-63-4 Downstream products

  • 848613-18-3
    848613-18-3

    benzyl 2-methyl-3-phenylpropanoate

  • 108-88-3
    108-88-3

    toluene

  • 129823-43-4
    129823-43-4

    (Z)-((1-(benzyloxy)prop-1-en-1-yl)oxy)trimethylsilane

  • 129823-42-3
    129823-42-3

    1-(Benzyloxy)-1-<(trimethylsilyl)oxy>prop-1-ene

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