4-tert-Butylcyclohexanol

  • Name: 4-tert-Butylcyclohexanol
  • CAS: 98-52-2
  • Purity: 99%
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Details

Buy Quality 4-tert-Butylcyclohexanol 98-52-2 In Stock with Immediately Delivery

  • Molecular Formula: C10H20O
  • Molecular Weight: 156.268
  • Appearance/Colour: white powder or granules 
  • Vapor Pressure: 6-201.38Pa at 25-65℃ 
  • Melting Point: 60-69 °C 
  • Refractive Index: 1.447  
  • Boiling Point: 214.2 °C at 760 mmHg 
  • PKA: 15.32±0.40(Predicted) 
  • Flash Point: 105 °C 
  • PSA： 20.23000 
  • Density: 0.92 g/cm3 
  • LogP: 2.58360 

4-tert-Butylcyclohexanol(Cas 98-52-2) Usage

Synthesis

Phenol and isobutylene carry out tert-butylation reaction in the presence of aluminum trichloride, and catalytic hydrogenation with Rays Nickel W7, two kinds of geometric structures can be obtained, in which the trans structure accounts for more than 70%.

Preparation

From 4-terf-butylphenol by hydrogenation(Arctander, 1969).

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 2724, 1980 DOI: 10.1021/jo01301a040Synthesis, p. 171, 1977 DOI: 10.1055/s-1977-24307

InChI:InChI=1/C10H20O/c1-10(2,3)8-4-6-9(11)7-5-8/h8-9,11H,4-7H2,1-3H3

98-52-2 Relevant articles

UNUSUAL HIGH REACTIVITIES OF 5α- AND 5β-CHOLESTAN-3-ONES IN THE HYDROGENATION CATALYZED BY PALLADIUM. EVIDENCE FOR AN ATTRACTIVE INTERACTION OF THE STEROID α-FACE WITH PALLADIUM

Nishimura, Shigeo,Murai, Mikio,Shiota, Michio

, p. 1239 - 1242 (1980)

5α- And 5β-cholestan-3-ones are 30 and 1...

SOMC?Periodic Mesoporous Silica Nanoparticles: Meerwein-Ponndorf-Verley Reduction Promoted by Immobilized Rare-Earth-Metal Alkoxides

Anwander, Reiner,Bock, Lorenz,Kramer, Markus,Liang, Yucang,Maichle-M?ssmer, C?cilia,Tran, Xuan

, p. 1046 - 1058 (2020)

The Meerwein-Ponndorf-Verley (MPV) reduc...

A direct conversion of aldohexopyranose to ketohexopyranose benzyl derivatives by Meerwein-Ponndorf/Oppenauer reaction induced by air-oxidised samarium diiodide

Adinolfi, Matteo,Iadonisi, Alfonso,Mangoni, Lorenzo

, p. 5987 - 5988 (1996)

2,3,4,6-tetra-O-benzyl-D-galactopyranose...

Half-sandwich rhodium complexes with phenylene-based SCS ligands: Synthesis, characterization and catalytic activities for transfer hydrogenation of ketones

Jia, Wei-Guo,Gao, Li-Li,Zhi, Xue-Ting,Li, Xiao-Dong,Wang, Zhi-Bao,Sun, Ying

, (2020/12/30)

A series of half-sandwich rhodium comple...

Postsynthetic Modification of Half-Sandwich Ruthenium Complexes by Mechanochemical Synthesis

Jia, Wei-Guo,Zhi, Xue-Ting,Li, Xiao-Dong,Zhou, Jun-Peng,Zhong, Rui,Yu, Haibo,Lee, Richmond

, p. 4313 - 4321 (2021/05/04)

A mild and environmentally friendly meth...

Aromatic compound hydrogenation and hydrodeoxygenation method and application thereof

-

Paragraph 0094-0096; 0098; 0100-0104, (2021/05/29)

The invention belongs to the technical f...

Base-free transfer hydrogenation of aryl-ketones, alkyl-ketones and alkenones catalyzed by an IrIIICp* complex bearing a triazenide ligand functionalized with pyrazole

Medrano-Castillo, Layla J.,Collazo-Flores, Miguel á.,Camarena-Díaz, Juan P.,Correa-Ayala, Erick,Chávez, Daniel,Grotjahn, Douglas B.,Rheingold, Arnold L.,Miranda-Soto, Valentín,Parra-Hake, Miguel

, (2020/03/13)

An IrIIICp* complex (2) bearing a triaze...

98-52-2 Process route

C<sub>18</sub>H<sub>22</sub>O

C18 H22 O

tert-butylbenzene
253185-03-4,253185-04-5

tert-butylbenzene

tert-butylcyclohexane
3178-22-1

tert-butylcyclohexane

4-(1,1-dimethylethyl)-cyclohexanol
98-52-2

4-(1,1-dimethylethyl)-cyclohexanol

Conditions
Conditions Yield
Multi-step reaction with 2 steps
1: hydrogen / water / 3 h / 270 °C / 16501.7 Torr
2: hydrogen / water / 2 h / 270 °C / 15001.5 Torr
With hydrogen; In water;
para-tert-butylphenol
98-54-4

para-tert-butylphenol

tert-butylbenzene
253185-03-4,253185-04-5

tert-butylbenzene

tert-butylcyclohexane
3178-22-1

tert-butylcyclohexane

4-(1,1-dimethylethyl)-cyclohexanol
98-52-2

4-(1,1-dimethylethyl)-cyclohexanol

Conditions
Conditions Yield
With hydrogen; In water; at 270 ℃; for 2h; under 15001.5 Torr; Reagent/catalyst;

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